Thermodynamic and kinetic study of synthesised graphene oxide-CuO nanocomposites: A way forward to fuel additive and photocatalytic potentials

阅读量:

15

摘要:

Rectangular shaped GO-CuO nanocomposites have gained special attention because of spectacular applications in wastewater treatment. However, due to a lack of research, the fuel additive properties of GO-CuO are still unreported. A proper synthesis and characterisation methods are necessary to investigate the fuel additive properties of GO-CuO. The present research demonstrates the synthesis of graphene oxide (GO) sheets via modified Hummers' method. Further, GO-CuO nanohybrid was prepared by fast, cost-effective, and easy to handle solvothermal approach. The crystal data such as crystal structure, unit cell parameters, space groups, crystal system, and coordinates were explained via XRD analysis. Physical and combustion properties of fuel were analysed at different concentrations (0, 20, 40, 60, and 80ppm) of diesel-GO-CuO blend for fuel quality parameters. The flash point and fire point of pure diesel oil were observed as 78 and 80°C which were decreased to 50 and 58°C, respectively, at 80ppm concentration. With GO-CuO nanocomposites, the cloud point and pour point decrease until a temperature of 8°C and 19°C, respectively, with a pronounced decrease in the viscosity up to 1.83mm2/s. Further, the photocatalytic degradation of Methylene Red (MR) dye is studied with the effect of changing H2O2, photocatalyst, and dye concentrations with time. Remarkably, the reaction kinetics and MR degradation of about 94% with sixth-time recyclability were observed. The results of this study showed improved MR degradation when using GO-CuO with H2O2. GO-CuO applications can be utilised to remove other dyes in future and to improve fuel quality parameters.

展开

DOI:

10.1016/j.molliq.2020.113494

年份:

2020

通过文献互助平台发起求助,成功后即可免费获取论文全文。

相似文献

参考文献

引证文献

来源期刊

站内活动

辅助模式

0

引用

文献可以批量引用啦~
欢迎点我试用!

关于我们

百度学术集成海量学术资源,融合人工智能、深度学习、大数据分析等技术,为科研工作者提供全面快捷的学术服务。在这里我们保持学习的态度,不忘初心,砥砺前行。
了解更多>>

友情链接

百度云百度翻译

联系我们

合作与服务

期刊合作 图书馆合作 下载产品手册

©2025 Baidu 百度学术声明 使用百度前必读

引用