New Reaction Mode of the Dieckmann-Type Cyclization under the Lewis Acid-Et <sub/>3</sub> N Conditions

阅读量:

11

作者:

S TamaiH UshirogochiS SanoY Nagao

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摘要:

Dieckmann-type cyclization reactions of various dicarboxylic acid derivatives were readily promoted by employing Lewis acids such as AlCl3, MgBr2, MgCl2, and Sn(OSO2CF3)2 in the presence of Et3N or N-ethylpiperidine. The cyclization reactions of half thiol diesters under the AlCl3-Et3N conditions exhibited different chemoselectivity from the cyclization under the basic conditions.

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DOI:

10.1246/cl.1995.295

年份:

1995

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