Intramolecular and intermolecular hydroxyl reactivity differences in ginkgolides A, B and C and their chemical applications

阅读量:

45

作者:

EJ CoreyKS RaoAK Ghosh

展开

摘要:

An investigation of the chemistry of ginkgolides A, B and C ( 1 ) has revealed an unusual interaction between the hydroxyl groups at C(1) and C(10) which activates their deprotonation to give 2 and provides a method for the interconversion of 1C and 1B . The ginkgolide 7-enol system 7 is more stable than the corresponding 7-keto form 6 , which is easily made by selective Jones oxidation of ginkgolide C.

展开

DOI:

10.1016/S0040-4039(00)60905-X

被引量:

1182

年份:

1992

通过文献互助平台发起求助,成功后即可免费获取论文全文。

我们已与文献出版商建立了直接购买合作。

你可以通过身份认证进行实名认证,认证成功后本次下载的费用将由您所在的图书馆支付

您可以直接购买此文献,1~5分钟即可下载全文,部分资源由于网络原因可能需要更长时间,请您耐心等待哦~

身份认证 全文购买

相似文献

参考文献

引证文献

来源期刊

Tetrahedron Letters
1992/11/10

引用走势

2010
被引量:178

辅助模式

0

引用

文献可以批量引用啦~
欢迎点我试用!

引用