Diastereoselective Reduction of Bicyclic ‐Enamino Carbonyl Piperidines – Application to the Total Synthesis of (–)‐Deoxocassine
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11
摘要：
The chemo- and diastereoselective reduction of chiral piperidine -enamino esters 4 and 6 and -enamino ketones 5 and 7 was studied and found to afford 2,3- or 2,3,6-substituted piperidines. This approach was successfully applied to the total synthesis of (-)-deoxocassine. ( Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)
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DOI：
10.1002/ejoc.200600777
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年份：
2010
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