Endohedral Cluster Compounds: Inclusion of Helium within C and C through Collision Experiments

来自 EBSCO

阅读量:

52

摘要:

Is host-guest chemistry possible with fullerenes? Yes, but not as easily as once thought in the euphoric first weeks of preparative fullerene chemistry. Although the occurrence of metal-ion inclusion is still controversial, indisputable evidence for inclusion of He-3 and He-4 within C60.+ and C70.+ radical ions has now been obtained. A reaction was initiated by collision of C60.+ and C70.+ ions with H2, D2, Ar, SF6, and He gases, but only He could be included, which agrees with the results of the initial calculations.

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DOI:

10.1002/anie.199108841

被引量:

919

年份:

1991

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来源期刊

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2010
被引量:137

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