POLYESTER GRAFT COPOLYMERS, FLEXIBLE COATING COMPOSITIONS COMPRISING SAME AND BRANCHED POLYESTER MACROMERS FOR PREPARING SAME

阅读量:

88

申请(专利)号:

EP19860310232

申请日期:

1986-12-31

公开/公告号:

EP0231666A3

公开/公告日期:

1988-07-13

申请(专利权)人:

E.I. DU PONT DE NEMOURS AND COMPANY

发明人:

PI KordomenosRR Ann

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被引量:

112

摘要:

Hydroxy functional polyester graft copolymers are provided. The copolymer is crosslinkable by hydroxy-reactive crosslinking agent and, in particular, is suitable for use in thermosetting coating compositions adapted to form a flexible cured coating over a variety of substrates, such as metal and plastic. The copolymer has a number average molecular weight between about 1000 and about 15,000, has a hydroxyl number between about 30 and about 300, and is the reaction product of carbon-carbon double bond-reactive monoethylenically unsaturated monomer with hydroxy functional carbon-carbon double bond-bearing branched polyester macromer. The macromer is the reaction product of (i) epoxy acrylate having the formula: with (ii) hydroxy functional polyester reactant containing 0-10 urethane linkages per molecule.

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