POLYESTER GRAFT COPOLYMERS, FLEXIBLE COATING COMPOSITIONS COMPRISING SAME AND BRANCHED POLYESTER MACROMERS FOR PREPARING SAME
申请(专利)号:
EP19860310232
申请日期:
1986-12-31
公开/公告号:
EP0231666A3
公开/公告日期:
1988-07-13
申请(专利权)人:
E.I. DU PONT DE NEMOURS AND COMPANY
被引量:
摘要:
Hydroxy functional polyester graft copolymers are provided. The copolymer is crosslinkable by hydroxy-reactive crosslinking agent and, in particular, is suitable for use in thermosetting coating compositions adapted to form a flexible cured coating over a variety of substrates, such as metal and plastic. The copolymer has a number average molecular weight between about 1000 and about 15,000, has a hydroxyl number between about 30 and about 300, and is the reaction product of carbon-carbon double bond-reactive monoethylenically unsaturated monomer with hydroxy functional carbon-carbon double bond-bearing branched polyester macromer. The macromer is the reaction product of (i) epoxy acrylate having the formula: with (ii) hydroxy functional polyester reactant containing 0-10 urethane linkages per molecule.
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