Catalytic, Enantioselective Synthesis of -Aminonitriles with a Novel Zirconium Catalyst
摘要:
Strecker reactions of aldimines with Bu3SnCN in the presence of the novel chiral zirconium binuclear catalyst 1 provide -aminonitriles in good yields and with high enantioselectivities. The reaction can be applied to a wide range of substrates. Since both enantiomers of the chiral sources are readily avaibable, both enantiomers of the -aminonitriles are easily prepared according to this method. L=N-methylimidazole.
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DOI:
10.1002/(SICI)1521-3773(19981204)37:22<3186::AID-ANIE3186>
被引量:
年份:
1998
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