摘要：

Shifty business: The use of propargylic esters in Au‐based catalysis results in the synthesis of an impressive variety of products as a function of the pendant groups' functionalities. Skeletal rearrangement by 1,2‐ and 1,3‐migration results in gold–carbene and allene intermediates, respectively. <img class="figure__image" src="https://wol-prod-cdn.literatumonline.com/cms/attachment/8e38fcb9-a881-45da-aab1-3e868cacadfd/mcontent.gif" data-lg-src="https://wol-prod-cdn.literatumonline.com/cms/attachment/660aef10-009a-4e86-b897-4da7b520bff9/mcontent.jpg">

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