Synthesis and reactivity of cobalt boryl complexes
摘要：
The reaction between [Co(PMe3)4] and B2(4-Mecat)2(4-Mecat = 1,2-O2-4-MeC6H3) or between [Co(PMe2Ph)4] and B2(cat)2(cat = 1,2-O2C6H4) affords the paramagnetic Co(ii) bisboryl complexes [Co(PMe3)3B(4-Mecat)2] and [Co(PMe2Ph)3B(cat)2] respectively, both of which have been structurally characterised. ESR data and preliminary diboration and boryl transfer reactivity studies are also presented. The reaction between [CoMe(PMe3)4] and B2(cat)2affords the Co(i) monoboryl complex [Co(PMe3)4B(cat)].
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DOI：
10.1039/b516594f
被引量：
年份：
2006
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