Total Synthesis of Biselide A, A Cytotoxic Macrolide of Marine Origin
摘要：
The total synthesis of biselide A based on our earlier strategy of synthesizing haterumalides is reported. The highlights of this approach are the use of regioselective enzymatic hydrolysis for the installation of a C20 oxygen functional group and an asymmetric aldol reaction for the stereoselective introduction of a C3 oxygen functional group.
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关键词：
biselide A haterumalides macrolide regioselective enzymatic hydrolysis asymmetric aldol reaction
DOI：
10.1055/s-0036-1588169
年份：
2017
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