Synthesis, spectral characterization of biologically active compounds derived from oxalyldihydrazide and 5-tert-Butyl-2-hydroxy-3-(3-phenylpent-3-yl) benzaldehyde and their Cu(II), Ni(II) and Co(II) Complexes
摘要:
A series of Schiff base M(II) complexes of the type [HLMClH2O] and [HLMOAcH2O], where M =Cu(II), Ni(II) and Co(II) have been synthesized by condensation of 3-tert-butl-2-hydroxy-3-(3-phenylpent-3-yl)benzaldehyde and oxalyldihydrazide (2:1) in the presence of divalent metal salt in methanolic medium. Thecomplexes have been characterized with the help of elemental analysis, conductance measurements, magneticmeasurements and their structural configuration have been determined by various spectroscopic (electronic, IR,1H NMR, 13C NMR, GCMS) techniques. Electronic and magnetic moments of the complexes indicate that thegeometries of the metal centers were octahedral. These metal complexes were also tested for their antimicrobialactivities to assess their inhibiting potential.
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年份:
2011
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