ChemInform Abstract: Highly Diastereo‐ and Enantioselective CuH‐Catalyzed Synthesis of 2,3‐Disubstituted Indolines.
摘要:
Cu-catalyzed reductive cyclization of arylimines, derived from ortho-amino styrenes, in the presence of (S,S)-Ph-BPE as chiral ligand constitutes a highly diastereo- and enantioselective synthesis of cis-2,3-disubstituted indolines.
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关键词:
indole derivatives, isoindole derivatives ring closure reactions, annulation reactions diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism) catalysis, phase‐transfer catalysis
DOI:
10.1002/chin.201537143
被引量:
年份:
2015
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