New Copper Clusters Containing Se and PEt3 as Ligands: [Cu70Se35(PEt3)22] and [Cu20Se13(PEt3)12]

来自 Wiley

阅读量:

33

作者:

D FenskeDCH Krautscheid

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摘要:

The largest cluster so far characterized X-ray crystallographically is formed together with a little 2 (structure: figure on right) in the reaction of CuCl with Se(SiMe3)2 and PEt3. An intermediate en route to 1 could be a Cu9 cluster. On heating 1 to 160-degrees-C Cu2Se is formed.

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DOI:

10.1002/anie.199014521

被引量:

232

年份:

1990

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2010
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