Allylic amination of alkenes by tosyliminoiodobenzene: manganese porphyrins as suitable catalysts
摘要：
Manganese-porphyrins and particularly Mn(TPP)(ClO4) were found to be much better catalysts than iron-porphyrins for allylic N-tosylamination of alkenes by tosyliminoiodobenzene. With the former catalysts, cyclohexene was selectively transformed into 3-tosylaminocyclohexene with yields up to 70% and cis- and trans-hex-2-ene into allylic N-tosylamines with yields around 40%, whereas cyclooctene led to the corresponding allylic and homoallylic N-tosylamines.
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DOI：
10.1016/S0040-4039(00)82081-X
被引量：
年份：
1988
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