Mild and General Conditions for Negishi Cross‐Coupling Enabled by the Use of Palladacycle Precatalysts
摘要：
A wide range of biaryls were synthesized by palladium-catalyzed Negishi cross-couplings at ambient temperature or with low catalyst loading. This protocol features the use of a recently reported aminobiphenyl palladacycle precatalyst to generate the catalytically active XPhosPd0 species. Significantly, a wide range of challenging heterocyclic and polyfluorinated aromatic substrates can be employed to give products in excellent yields.
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关键词：
cross-coupling heterocycles homogeneous catalysis organozinc reagents palladacycle precatalysts
DOI：
10.1002/anie.201207750
被引量：
年份：
2013
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