[Cu44Se22(PEt2Ph)18] and [Cu44Se22(PnButBu2)12]: Synthesis and Structure of Two Copper Clusters with Isomeric Cu?Se Frameworks
摘要:
The results of ab initio calculations for the sulfur-bridged copper clusters [Cu2nSn(PR3)m] (n = 1–4, 6; m = 0, 2, 4, 6, 8; RH, CH3) were compared with those of theoretical investigations of the selenium-containing analogues that have been recently reported. The theoretical work was carried out in order to find a possible explanation for the experimentally observed–different–properties of both...
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DOI:
10.1002/anie.199422871
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年份:
1994
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来源期刊
Angewandte Chemie International Edition
1994/12/05
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2010
被引量:80
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