[Cu44Se22(PEt2Ph)18] and [Cu44Se22(PnButBu2)12]: Synthesis and Structure of Two Copper Clusters with Isomeric Cu?Se Frameworks

阅读量:

31

作者:

S DehnenD Fenske

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摘要:

The results of ab initio calculations for the sulfur-bridged copper clusters [Cu2nSn(PR3)m] (n = 1–4, 6; m = 0, 2, 4, 6, 8; RH, CH3) were compared with those of theoretical investigations of the selenium-containing analogues that have been recently reported. The theoretical work was carried out in order to find a possible explanation for the experimentally observed–different–properties of both...

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DOI:

10.1002/anie.199422871

被引量:

292

年份:

1994

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来源期刊

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2010
被引量:80

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