4C/3E RADICAL CATIONS WITH CAGE-DIRECTED CONFIGURATIONS
阅读量：
11
摘要：
The selective oxidation of 2-propanethiolate on oxygen-covered Rh(111) was studied using temperature programmed reaction and high resolution electron energy loss spectroscopy. On Rh(111)-p(2x1)-O, reaction is proposed to proceed through carbon-sulfur bond breakage, affording 2-propyl followed by rapid beta-hydrogen elimination to propene or oxygen addition to 2-propoxide. The 2-propoxide immediately reacts t
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DOI：
10.1002/anie.199510161
被引量：
年份：
2010
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