Nucleophilic cleavage of acetals using organometallic reagents
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26
摘要：
A highly chemo- and stereo-selective cleavage of acetals derived from ()(2 R ,4 R )-2,4-pentanediol with organoaluminum and organotitanium reagents has been demonstrated. The reactions proceed under mild conditions with excellent yields and high chemoselectivities to give, after removal of the auxiliary, chiral alcohols of high enantiomeric purities.
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DOI：
10.1016/0022-328X(85)87359-9
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年份：
1985
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来源期刊
Journal of Organometallic Chemistry
16 April 1985
引用走势
2010
被引量：42
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