ChemInform Abstract: Exploring the in situ Utilization of Cyclic Imine Intermediates Generated by Isocyanoacetate Cycloaddition: Convergent Assembly of cis‐3a,8a‐Hexahydropyrrolo[2,3‐b]indole Scaffolds.
摘要：
Hexahydropyrroloindoles are synthesized from isocyanoacetates and electron-deficient olefins through a Cu(II) or Ag(I) catalyzed formal [3+2] cycloaddition, intramolecular nucleophilic addition, and protonation sequence.
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关键词：
fused pyrrole derivatives cascade reactions, domino reactions, tandem reactions catalysis, phase‐transfer catalysis
DOI：
10.1002/chin.201507174
年份：
2015
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