Enantiomeric Recognition and Interactions
摘要:
The consequences in a chemical reaction of the non-bonding interactions between molecules of one configuration on the one hand, and molecules of opposite configuration on the other hand are discussed. The reaction rates and product ratios in the reaction of a chiral compound depend upon the enantiomeric excess of the substrate. An antipodal interaction effect is observed in a phenol coupling reaction, a reductive camphor dimerization and a camphor reduction.
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DOI:
10.1016/0040-4020(76)80131-7
被引量:
年份:
1976
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