Photoinduced magnetic pole inversion in a ferro–ferrimagnet: (Fe0.40IIMn0.60II)1.5CrIII(CN)6
摘要：
We tried to design the magnet exhibiting magnetic pole (N and S) inversion by photostimuli. The magnetization of Fe1.5IICrIII(CN)67.5H2O was changed in a photon mode by visible light. A ferro-ferrimagnet (Fe0.40IIMn0.60II)1.5CrIII(CN)67.5H2O mixed by ferromagnetic (Fe–Cr system showing the change of magnetization by optical stimuli) site and ferrimagnetic (Mn–Cr system showing no optical response) site showed negative magnetization at the temperature lower than compensation temperature (Tcomp=19 K). In this mixed metal cyanide magnet we have succeeded in demonstrating a novel magnetic behavior "photoinduced magnetic pole inversion." Moreover, the magnetic pole inversion can be induced repeatedly by alternate optical and thermal stimulations.
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关键词：
chromium compounds ferrimagnetic materials iron compounds magnetisation manganese compounds organometallic compounds photomagnetic effect 7550Gg 7550Ww 7560Ej
DOI：
10.1063/1.118475
被引量：
年份：
1998
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