Enantioselective addition of dialkylzincs to aldehydes promoted by chiral amino alcohols. Mechanism and nonlinear effect
摘要：
A new perspective on traditional energy minimization problems is provided by a connection between statistical thermodynamics and combinatorial optimization (finding the minimum of a function depending on many variables). The joint use of a new method for uncovering the global minimum of intramolecular potential energy functions, based on following the asymptotic behavior of a system of stochastic differential equations, and an iterative-improvement technique, whereby a search for relative minima is made by carrying out local quasi-Newton minimizations starting from many distinct points of the energy hypersurface, proved most effective for investigating the low-energy conformational space of molecules.
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DOI：
10.1002/chin.198935092
被引量：
年份：
1989
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