Theory of the d10–d10 Closed‐Shell Attraction: 1. Dimers Near Equilibrium

We study the dependence of the aurophilic attraction (AuI–AuI) in perpendicular model systems of the type [(ClAuPH3)2] on the ab initio method, basis set ...

Pekka Pyykkö，N Runeberg，Fernando Mendizabal - 《Chemistry – A European Journal》

Silylimido and Disilylamido Groups as Clustering Centers for (Phosphane)gold(I) Units: Aurated Silylammonium Cations

The reaction of hexamethyldisilazane with tris[(phosphane)-aurio(I)]oxonium tetrafluoroborates affords the corresponding trinuclear 渭3-trimethylsilylimido...

K Angermaier，H Schmidbaur - 《European Journal of Inorganic Chemistry》

Three- and Four-Coordinate Gold(I) Complexes

Numerous reports describe the photoluminescence of two- and three-coordinate gold(I)-phosphine complexes, but emission in their analogous four-coordinate complexes is almost unknown. This work examines the luminescence of tetrahedral gol...

MC Gimeno，A Laguna - 《Chemical Reviews》

Encapsulated, Sandwiched, or Sticking Out: Closed-Shell Interactions of d10 Metal Centers with Thallium(I)

ChemInform is a weeklying Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInformof ...

LH Gade - 《Cheminform》

Theory of the d10–d10 Closed‐Shell Attraction: 1. Dimers Near Equilibrium

We study the dependence of the aurophilic attraction (AuIAuI) in perpendicular model systems of the type [(ClAuPH3)2] on the ab initio method, basis set an...

Pekka Pyykk，N Runeberg，F Mendizabal - 《Chemistry – A European Journal》

New Advances in Gold Catalysis Part II

Some of the unique features of gold catalysis were described in Part 1. Further examples of reactions catalysed by supported transition metal oxides are gi...

D Thompson - 《Gold Bulletin》

Metal-metal interactions in chain compounds of gold(I): syntheses and crystal structures of chlorotetrahydrothiophenegold(I), bromotetrahydrothiophenegold(...

The crystal structures of the title compounds have been determined from X-ray intensity data collected at 200 K with a CAD 4 diffractometer. Crystal data a...

S Ahrland，K Dreisch，Noren, B.，... - 《Materials Chemistry & Physics》

Aurophilicity: the effect of the neutral ligand L on [{ClAuL}(2) ] systems.

The effect of the ligand L on the aurophilic AuIAuI closed-shell interaction in perpendicular [{ClAuL}2] model systems is investigated. An analogous study ...

J Muñiz，C Wang，P Pyykkö - 《Chemistry》

Theoretical and photoluminescence studies on the d10-s2 AuI-TlI interaction in extended unsupported chains.

The reactions of solutions of TlPF 6 and OPPh 3 in tetrahydrofuran or acetone with NBu 4 [AuR 2 ] (R=C 6 Cl 5 , C 6 F 5 ) gave the new complexes [Au(C 6 ...

EJ Fernández，A Laguna，JM López-De-Luzuriaga，... - Chemistry - A European Journal

Gold complexes with selenium ligands. Part 7. Synthesis and crystal structures of oligonuclear gold(I)-selenolate complexes

Cationic and neutral Oligonuclear organophosphinegold(I) complexes with organic selenolate ligands SeR [R = Ph, CH₂Ph, C₆H₄

Wolfgang，Eikens，Carsten，... - 《Journal of the Chemical Society》