Novel, Short, Stereospecific Synthesis of lyxo-(2R,3R,4R)-Phytosphingosine and erythro-(2R,3S)-Sphingosine
摘要：
Lyxo-phytosphingosine and erythro-sphingosine have been elaborated from a common intermediate. The key step in the reaction sequence involves stereo- and regiospecific functionalization of an olefin by intramolecular nucleophilic sulfinyl group participation.
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DOI：
10.1021/jo034157w
被引量：
年份：
2003
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