Microwaves in organic synthesis. Thermal and non-thermal microwave effects
摘要：
Microwave irradiation has been successfully applied in organic chemistry. Spectacular accelerations, higher yields under milder reaction conditions and higher product purities have all been reported. Indeed, a number of authors have described success in reactions that do not occur by conventional heating and even modifications of selectivity chemo-, regio- and stereoselectivity. The effect of microwave irradiation in organic synthesis is a combination of thermal effects, arising from the heating rate, superheating or "hot spots" and the selective absorption of radiation by polar substances. Such phenomena are not usually accessible by classical heating and the existence of non-thermal effects of highly polarizing radiation—the "specific microwave effect"—is still a controversial topic. An overview of the thermal effects and the current state of non-thermal microwave effects is presented in thiscritical reviewalong with a view on how these phenomena can be effectively used in organic synthesis.
展开
DOI：
10.1039/b411438h
被引量：
年份：
2005
Wiley
万方医学
Semantic Scholar
Semantic Scholar
(全网免费下载)
掌桥科研
查看更多
dx.doi.org
Ingenta
RSC publishing
NCBI
RSC publishing
(全网免费下载)
Oxford Univ Press
JSTOR
Europe PMC
NCBI
ResearchGate
ResearchGate
(全网免费下载)
EBSCO
chem.ccu.edu.tw
(全网免费下载)
140.123.79.90
(全网免费下载)
rstb.royalsocietypublishing.org
www.socolar.com
scindeks.ceon.rs
esl.ecsdl.org
SAGE
findarticles.com
cghjournal.org
pubfacts.com
mendeley.com
onAcademic
t.co
scienceopen.com
deepdyve.com
sustainablechemicalprocesses.com
jacionline.org
Semantic Scholar
(全网免费下载)
RSC publishing
(全网免费下载)
ResearchGate
(全网免费下载)
140.123.79.90
(全网免费下载)
chem.ccu.edu.tw
(全网免费下载)
通过文献互助平台发起求助，成功后即可免费获取论文全文。
相似文献
参考文献
引证文献
引用走势
站内活动
辅助模式
引用
文献可以批量引用啦~
欢迎点我试用！
