Solubility and Partitioning. 3. The Solubility of Halobenzenes in Water

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68

作者:

SH YalkowskyRJ OrrSC Valvani

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摘要:

The aqueous molar solubilities S//w of 26 mono- and multi-halogenated benzenes at 25 plus or minus 1 degree C were determined. These values, along with values obtained from the literature for nine additional compounds, can be estimated by log S//w equals minus 0. 0095(MP)- 0. 9874 log (PC) plus 0. 7178, where (MP) is the melting point in degree C and (PC) is the estimated octanol-water partition coefficient for each halobenzene. The data were also found to be in agreement with log S//w equals minus 0. 0103(MP)- 0. 04225(TSA) plus 3. 2970, where (TSA) is the total molecular surface area of the halobenzene.

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DOI:

10.1021/i160072a011

被引量:

1199

年份:

1979

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2010
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