Regio- and chemoselective metalation of arenes and heteroarenes using hindered metal amide bases.
摘要：
The preparation of highly functionalized organometallic compounds can be achieved by direct C H activation of a broad range of unsaturated substrates using lithium chloride solubilized 2,2,6,6-tetramethylpiperidide bases (TMP n MX m pLiCl). These are excellent reagents for converting a wide range of aromatic and heterocyclic substrates into valuable organometallic reagents with broad applications in organic synthesis.
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DOI：
10.1002/anie.201101960
被引量：
年份：
2011
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