Sorption of carboxylic acid from carboxylic salt solutions at PHS close to or above the pK.sub.a of the acid, with regeneration with an aqueous solution of ammonia or low-molecular-weight alkylamine
申请(专利)号:
US19910697315
申请日期:
1991-05-07
公开/公告号:
US5132456A
公开/公告日期:
1992-07-21
申请(专利权)人:
THE REGENTS OF THE UNIVERSITY OF CALIFORNIA
被引量:
摘要:
Carboxylic acids are sorbed from aqueous feedstocks at pHs close to or above the acids' pH.sub.a into a strongly basic organic liquid phase or onto a basic solid adsorbent or moderately basic ion exchange resin. the acids are freed from the sorbent phase by treating it with aqueous alkylamine or ammonia thus forming an alkylammonium or ammonium carobxylate which dewatered and decomposed to the desired carboxylic acid and the alkylamine or ammonia.
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