Thermodynamics of aqueous solutions of isomeric sugars
摘要：
The excess enthalpies of ternary aqueous solutions, containing pairs of monosaccharides and their derivatives, were determined in order to ascertain whether it is possible (in spite of the prevailing solute-solvent interactions that mai n ly characterize the properties of these mixtures) to reveal the existence of weak stereospecific interactions. For the two pairs of xylose and arabinose enantiomers this investigation was successful.
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关键词：
Experimental/ enthalpy molecular biophysics organic compounds organic molecule configurations solutions thermodynamic properties/ thermodynamics ternary sugars xylose enantiomers aqueous solutions isomeric sugars excess enthalpies pairs of monosaccharides solute-solvent interactions weak stereospecific interactions arabinose enantiomers/ A6550 Thermodynamic properties and entropy A8260L Thermodynamics of solutions A8715D Physical chemistry of biomolecular solutions condensed states
DOI：
10.1016/0378-3812(85)90034-2
被引量：
年份：
1985
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