Thermodynamics of aqueous solutions of isomeric sugars
摘要:
The excess enthalpies of ternary aqueous solutions, containing pairs of monosaccharides and their derivatives, were determined in order to ascertain whether it is possible (in spite of the prevailing solute-solvent interactions that mai n ly characterize the properties of these mixtures) to reveal the existence of weak stereospecific interactions. For the two pairs of xylose and arabinose enantiomers this investigation was successful.
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关键词:
Experimental/ enthalpy molecular biophysics organic compounds organic molecule configurations solutions thermodynamic properties/ thermodynamics ternary sugars xylose enantiomers aqueous solutions isomeric sugars excess enthalpies pairs of monosaccharides solute-solvent interactions weak stereospecific interactions arabinose enantiomers/ A6550 Thermodynamic properties and entropy A8260L Thermodynamics of solutions A8715D Physical chemistry of biomolecular solutions condensed states
DOI:
10.1016/0378-3812(85)90034-2
被引量:
年份:
1985
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