Reactivity of 7-Substituted Camphenes. Structure of β-Isocamphor
摘要:
β-Isocamphor, the nitrous acid deamination product of camphenamine, has been shown to be anti-7-camphenol(Va). The solvolytic behavior of tosylates obtained from anti-7-camphenol, syn-7-camphenol and syn-7-camphanol, has been studied. 2,2,3-Trimethyl-3-cyclohexene-1-carboxaldehyde has been identified as the product resulting from the action of sulfuric acid on, β-isocamphor.
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DOI:
10.1021/ja01556a036
被引量:
年份:
1958
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