Reactivity of 7-Substituted Camphenes. Structure of β-Isocamphor

来自 ACS

阅读量:

31

作者:

van Tamelen, Eugene E.Judd, Claude I.

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摘要:

β-Isocamphor, the nitrous acid deamination product of camphenamine, has been shown to be anti-7-camphenol(Va). The solvolytic behavior of tosylates obtained from anti-7-camphenol, syn-7-camphenol and syn-7-camphanol, has been studied. 2,2,3-Trimethyl-3-cyclohexene-1-carboxaldehyde has been identified as the product resulting from the action of sulfuric acid on, β-isocamphor.

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DOI:

10.1021/ja01556a036

被引量:

168

年份:

1958

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2002
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