Dissociation Energies of Diatomic Molecules of the Transition Elements. II. Titanium, Chromium, Manganese, and Cobalt
摘要：
Using information derived from a combination of effusion and mass‐spectrometric techniques, the dissociation energy of Co2has been calculated from the ratio of dimeric and monomeric cobalt in equilibrium with the liquid asD00(Co2)=39±6 kcal. Upper limits to the dissociation energy of Ti2, Cr2, and Mn2are also estimated asD00(Ti2)<58 kcal,D00(Cr2)<44 kcal,D00(Mn2)<21 kcal. These results are correlated with the energy required to promote the atom to the lowest‐lying bonding or valence state of electron configuration 3dn—14s.
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DOI：
10.1063/1.1725817
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年份：
1964
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来源期刊
The Journal of Chemical Physics
1964/12/15
引用走势
2008
被引量：21
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