Hydrothermal synthesis and electrochemical properties of a coordination polymer based on dinuclear (Pyrazinyl tetrazolate) Copper(II) cations and β-Octamolybdate Anions
摘要：
A hybrid compound (H 2 bbi)[Cu 2 (pzta) 2 (H 2 O) 2 ][ β -Mo 8 O 26 ] ( 1 ) (pztaH = 5-(2-pyrazinyl) tetrazolate, bbi = 1,1'-(1,4-butanediyl)bis(imidazole), has been hydrothermally synthesized and characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction. In 1 , the β -Mo 8 clusters link dinuclear copper (II) complexes as bidentate connectors to form inorganic-organic chains. These chains and the [H 2 bbi] 2+ counter-cations are fused together forming layers via hydrogen bonding interactions. The electrochemical properties of 1 were studied. The results indicate that 1 has an electrocatalytic activity towards the reduction of iodate ascribed to the Mo-centers.
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DOI：
10.1007/s12039-016-1076-2
被引量：
年份：
2016
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