Fluorine-Controlled C–H Borylation of Arenes Catalyzed by PSiN-Pincer Platinum Complex
摘要：
An efficient, regioselective synthesis of fluorine-substituted arylboronic esters was achieved through fluorine-controlled C–H borylation of arenes with diboron catalyzed by a PSiN–platinum complex. The promising utility of the PSiN–platinum catalyst and its unique regioselectivity were demonstrated for the first time, which would complement the well-developed Ir-catalyzed C–H borylation.
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关键词：
organo‐boron compounds halogen compounds (benzene compounds regioselective reactions catalysis, phase‐transfer catalysis
DOI：
10.1039/c5cc07263h
被引量：
年份：
2015
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