Geometries of and bonding in bi- and polynuclear metal complexes with bridging ligands
摘要：
The geometries of binuclear and polynuclear complexes of transition and main group metals having bridging groups X (X = halide), OR, SR, NR 2, PR 2, H and R (alkyl, aryl) are discussed. Previous rationales of the bridge stereochemistry in, for example, (BeCl 2) n and [Be(CH 3) 2] n are rejected and emphasis is placed on the symmetry of the molecular orbitals and their electron occupancy in electron deficient and electron precise species.
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DOI：
10.1016/S0022-328X(00)95088-5
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年份：
1973
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来源期刊
Journal of Organometallic Chemistry
1973/03/16
引用走势
1979
被引量：6
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