Tert-butylsulfonamide. A new nitrogen source for catalytic aminohydroxylation and aziridination of olefins.
摘要：
[reaction: see text] The N-chloramine salt of tert-butylsulfonamide has been shown to be an efficient nitrogen source and the terminal oxidant for catalytic aminohydroxylation and aziridination of olefins, resembling closely Chloramine-T by its behavior in these catalytic reactions. The sulfonyl-nitrogen bond in the product or its derivatives is easily cleaved under mild acidic conditions, allowing for facile liberation of the amino group.
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关键词：
Alkenes Nitrogen Sulfonamides Chloramines Amines Aziridines Oxidants Hydroxylation Catalysis Tosyl Compounds
DOI：
10.1021/ol990761a
被引量：
年份：
1999
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