Rh(II)-catalyzed intramolecular C-H insertion of diazo substrates in water: scope and limitations.
摘要：
Preferential Rh(II) carbenoid intramolecular C-H versus O-H insertion derived from alpha-diazo-acetamides can be achieved in water by using an appropriate combination of the catalyst and amide groups, which creates a larger hydrophobic environment around the reactive carbenoid center.
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关键词：
RHODIUM(II) CATALYZED-REACTIONS ORGANIC-REACTIONS ALPHA-DIAZOACETAMIDES N-ARYLDIAZOAMIDES YLIDE FORMATION DIRHODIUM(II) CARBENOIDS CYCLOPROPANATION SOLVENT ENANTIOSELECTIVITY
DOI：
10.1021/jo060397a
被引量：
年份：
2006
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