The bonding capabilities of transition metal clusters
摘要：
Electron-deficient alkyl complexes of transition metals sometimes exhibit striking structures in which the alkyl group is distorted in such a way that a C-H bond interacts with the metal atom, leading to an electron donation from the C-H bond to the metal and to a weakening of that bond. In particular, this is the case for the octahedral d0 complex 4. However, in the tetrahedral d0 complex 7,...
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关键词：
Theoretical or Mathematical/ bonds (chemical) inorganic molecule configurations metal clusters molecular orbitals calculations transition metal compounds/ bonding capabilities transition metal clusters stoichiometries transition metal cluster compounds extended Huckel calculations high lying antibonding orbitals cluster valence molecular orbitals ligand bonding tetrahedron octahedron/ A3120 Specific calculations and results for atoms and molecules A3520B General molecular conformation and symmetry stereochemistry
DOI：
10.1021/ja00485a011
被引量：
年份：
1978
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