Reactions of .alpha.,.beta.-epoxysilanes with organocuprate reagents. New stereospecific olefin synthesis

阅读量:

39

作者:

PF HudrlikD PetersonRJ Rona

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摘要:

α,β-Epoxysilanes react with organocuprate reagents in a regio- and stereospecific manner to give good yields of β-hydroxyalkylsilanes, which can be stereospecifically converted to olefins in high yield under mild conditions.

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DOI:

10.1021/jo00903a036

被引量:

372

年份:

1975

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