Naphthalene-catalysed lithiation of 3-chloro-2-chloromethyl-propene: A barbier-type practical alternative to the trimethylenemethane dianion
摘要：
The reaction of equimolar amounts of 3-chloro-2-chloromethylpropene ( 2 ) and a carbonyl compound ( 3 ) with an excess of lithium powder and a catalytic amount (6%) of naphthalene in tetrahydrofuran at 78°C leads, after hydrolysis with water, to the corresponding diols 4 in a Barbier-type process.
展开
关键词：
alkylation, arylation, dealkylation, dearylation, C‐acylation, olefination alcohols (acyclic compounds cyclopropane derivatives cyclohexane derivatives polyphenylalkene derivatives (stilbene derivatives
DOI：
10.1002/chin.199243119
被引量：
年份：
1992
相似文献
参考文献
引证文献
来源期刊
引用走势
辅助模式
引用
文献可以批量引用啦~
欢迎点我试用！
