Gold(I)-catalyzed asymmetric aldol reaction of N-methoxy-N-methyl-alpha-isocyanoacetamide...
摘要:
Investigates the asymmetric aldol reaction of N-methoxy-N-methyl-alpha-isocyanoacetamide (alpha-isocyano Weinreb amide) with aldehydes in the presence of a gold(I) catalyst. Formation of optically active oxazolines; Generation of N,O-protected beta-hydroxy alpha-amino aldehydes and ketones.
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年份:
1995
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