Theoretical studies of stereoselective hydroborations
摘要：
Asymmetric hydroborations of alkenes are outstanding examples of reactions which proceed with high acyclic stereoselection to give synthetically useful functionality. We have undertaken com- putational studies of these reactions as a part of our more general studies of stereoselective organic reactions. We wish to develop understanding of those factors which control stereoselectivity in known cases, and to develop both qualitative and quantitative methods to predict stereoselectivities of cases not yet investigated. Here, we detail our progress in understanding hydroborations, and in subsequent publications, we will report similar studies for other types of organic reactions, such as intermolecular and intramolecular cycloadditions, epoxidations, radical reactions, nucleophilic additions, and aldol condensations.
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DOI：
10.1016/0040-4020(84)80009-5
被引量：
年份：
1984
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