Organoboron Compounds. II. The Reducing Action of Some Organoboronic Acids1
摘要：
A protocol for the Pd(II)-catalyzed ortho-C-H alkylation of phenylacetic and benzoic acids using alkylboron reagents is disclosed. Mono-protected amino acid ligands (MPAA) were found to significantly promote reactivity. Both potassium alkyltrifluoroborates and alkylboronic acids were compatible coupling partners. The possibility of a radical alkyl transfer to Pd(II) was also investigated.
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DOI：
10.1021/ja01268a034
被引量：
年份：
1938
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