High-valent manganese and iron corrolazines: Effect of Lewis acids, atom and group transfer reactions
摘要：
High-valent manganese and iron complexes have been postulated as key intermediates in synthetic and biological processes. Insights into the reactivity and spectroscopic patterns of these species are of particular importance. However, study in these high-valent metal complexes has been challenging because of their inherent instability. The corrolazine ligand, a modified porphyrinoid framework, has been shown to stabilize a variety of high-valent metal ions. Access to stable, well-defined metal corrolazines provides an opportunity to directly examine the reactivity and spectroscopic signatures of these species. Preparation, characterization and reactivity studies of high-valent manganese and iron corrolazines are the main goal of this thesis.
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关键词：
Chemistry Inorganic chemistry High-valent manganese and iron corrolazines| Effect of Lewis acids atom and group transfer reactions THE JOHNS HOPKINS UNIVERSITY David Goldberg Leeladee Pannee
年份：
2012
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