Structure of the Polyanions of the Transition Metals in Aqueous Solution: The Hexatantalate
摘要:
Alkaline solutions of tantalum (V) have been studied by spectrophotometric, emf, and light scattering techniques. The position of the charge transfer band at about 2000 A did not change as the total tantalum concentration or the hydroxide ion concentration were varied. The emf measurements indicated that the compound K{sub 8}Ta{sub 6}O{sub 19} {center_dot} 16H{sub 2}O dissolves in dilute KOH solutions without appreciable protonation. The scattering of potassium 12-tungstosilicate was also studied as a check. Comparisons are made with structures for other poly-cations and anions which are found at high concentrations in monodisperse systems.
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关键词:
chemistry acidity alkalis compounds electric potential hydroxides light photometry potassium hydroxides potassium oxides
DOI:
10.1021/ic50009a026
被引量:
年份:
1963
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