Structure of the Polyanions of the Transition Metals in Aqueous Solution: The Hexatantalate

阅读量:

27

作者:

WH NelsonRS Tobias

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摘要:

Alkaline solutions of tantalum (V) have been studied by spectrophotometric, emf, and light scattering techniques. The position of the charge transfer band at about 2000 A did not change as the total tantalum concentration or the hydroxide ion concentration were varied. The emf measurements indicated that the compound K{sub 8}Ta{sub 6}O{sub 19} {center_dot} 16H{sub 2}O dissolves in dilute KOH solutions without appreciable protonation. The scattering of potassium 12-tungstosilicate was also studied as a check. Comparisons are made with structures for other poly-cations and anions which are found at high concentrations in monodisperse systems.

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DOI:

10.1021/ic50009a026

被引量:

123

年份:

1963

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来源期刊

Inorganic Chemistry
1963/10/01

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2012
被引量:10

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