Metal-Free Conversion of Methane and Cycloalkanes to Amines and Amides by Employing a Borylnitrene
摘要：
Chemical Equation Presented) C-H insertion: Borylnitrenes, which are generated in situ by photoylsis of azides, convert unactivated alkanes by intermolecular C-H insertion into aminoboranes (see scheme), which in turn can be reacted further to give amines or amides. The boryl group serves two purposes: it converts the nitrene into a highly reactive BN vinylidene analogue, and it is easily cleaved from the product.
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DOI：
10.1002/anie.200705936
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年份：
2010
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来源期刊
Angewandte Chemie International Edition
2010/5/14 0:00:00
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2010
被引量：22
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