Catalysis of alkene oxidation by nickel salen complexes using NaOCl under phase-transfer conditions

来自 ACS

阅读量:

43

作者:

H YoonCJ Burrows

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摘要:

New nickel catalysts have been developed for the oxidation of alkenes to epoxides, alcohols, aldehydes and ketones. Mechanistic studies indicate that the oxidation reactions are very sensitive to the nature of the catalyst; only certain ligands including salen and the macrocycles cyclam and dioxocyclam render Ni(II) effective as a catalyst. A Ni(III) or Ni(IV)-oxo species has been postulated...

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DOI:

10.1021/ja00220a086

被引量:

230

年份:

1988

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