Sur de nouvelles phases sulfurées ternaires du molybdène
摘要:
The authors describe the preparation of new sulfides of formula M IIMo nS n + 1. If M = Ag, Sn, Ca, Sr, Pb, Ba, they are stoichiometric; if M = Ni, Co, Fe, Cr, Mn, Cu, Mg, Zn, Cd, solid solutions are observed with 2 ⩽ n ⩽ 6. Another series of formula M 2Mo nS n + 1 was also prepared, where M = alkali metal and n = 2 or 5. The crystallographic properties are investigated: the phases obtained are generally rhomboedral, with an eventual triclinic distortion.
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DOI:
10.1016/0022-4596(71)90095-8
被引量:
年份:
1971
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1986
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