With the aim of modeling the arrangement of redox-active and photoactive components along the electron-transfer pathway of photosystem II, tetra- to nonanu...
Reduced Mn species [Mn(II,III)] released by reductive dissolution were readsorbed and restricted further abiotic oxidation of PCP by the MnO2 surface. A...
The reaction of [L2Mn2IV(-O)3](PF6)2, L=1,4,7-trimethyl-1,4,7-triazacyclononane (1) with a range of phenols (2–5) in aqueous solution at pH 10.5 has been ...
The nature of oxide in soil and associated environments in influencing the abiotic transformations of polyphenols still remains to be established. The obje...
BACKGROUND Mixed-valence manganese oxide nanoparticles (nano-MnOx) were prepared by the oxidation of Mn (II) with Mn-oxdizing bacteria Pseudomonas sp. G7. ...
Manganese(IV) complexes Mn(R-R′-sap)2, where H2(R-R′-sap) denotes 2-(salicylideneamino)phenols with the substituent R on the salicylaldehyde ring and the R′ on the o-aminophenol ring, were prepared by the oxidation of binuclear mangan...
Nature has evolved a variety of different metalloenzymes for the selective oxygenation of C–H bonds. Cytochrome P450s, for example, are heme proteins that...
This thesis describes the synthesis, characterization and reactivity of metal-triazacorrole complexes. There has been much interest in the field of corrole...
