Microwave-assisted Suzuki–Miyaura and Heck–Mizoroki cross-coupling reactions of aryl chlorides and bromides in water using stable benzothiazole-based palladium(II) precatalysts
摘要:
The catalytic activity of benzothiazole-based Pd(II)-complexes was evaluated in Suzuki–Miyaura and Heck–Mizoroki C–C cross-coupling reactions of aryl chlorides and bromides with olefins and arylboronic acids both under thermal as well as microwave irradiation conditions in water. The factors affecting the optimization of such reactions as well as the reusability of the Pd-precatalysts are studied.
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关键词:
Pd(II) precatalysts Microwave irradiation Suzuki–Miyaura Heck–Mizoroki cross-coupling reactions
DOI:
10.1016/j.tet.2007.07.029
被引量:
年份:
2007
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