Dendrizymes: Expanded ligands for enantioselective catalysis
摘要:
Dendrizymes are a new class of expanded ligands, designed for enantioselective catalysis with transition metal complexes. These expanded ligands consist of a strongly binding chelate core, which is surrounded by space-filling dendrimer substituents, built-up by branching units and optically active groups. In a complex of such a dendrimer ligand a reaction is supposed to take place in the same way as in the pocket of an enzyme.
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DOI:
10.1016/0022-328X(95)00507-M
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年份:
1995
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来源期刊
Journal of Organometallic Chemistry
September 1995
引用走势
2002
被引量:57
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